A Kinetic Investigation of a Carrier-Mediated Transport through a Bulk Liquid Membrane
نویسندگان
چکیده مقاله:
The kinetics of the potassium thiocyanate transport mediated by dicyclohexyl-18-crown-6 (L) through a bulk liquid membrane is studied experimentally and theoretically. The proposed model is based on the assumption of a pure diffusion of the complex salt [K·L]+SCN¯ through the liquid membrane stagnant films at the interfaces. It illustrates the connection between liquid-liquid extraction equilibrium data and transport rates. The evaluation of the transfer coefficient allows to evaluate the organic stagnant films thickness, the stationary state transport rate and the time lag.
منابع مشابه
a kinetic investigation of a carrier-mediated transport through a bulk liquid membrane
the kinetics of the potassium thiocyanate transport mediated by dicyclohexyl-18-crown-6 (l) through a bulk liquid membrane is studied experimentally and theoretically. the proposed model is based on the assumption of a pure diffusion of the complex salt [k·l]+scn¯ through the liquid membrane stagnant films at the interfaces. it illustrates the connection between liquid-liquid extraction equilib...
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عنوان ژورنال
دوره 25 شماره 4
صفحات 17- 23
تاریخ انتشار 2006-12-01
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